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41.
Poly(p-phenylene terephthalamide) (PPTA) was blended with poly(vinyl chloride) (PVC) by solution-blending method. PPTA was metalated for dissolving in dimethyl sulfoxide. Dimethyl sulfoxide was used as a common solvent. In PPTA/PVC composite, PPTA accelerated the thermal degradation of PVC. PPTA molecules are aggregated as microfibrillar form in PVC matrix. Such microfibrils are dispersed homogeneously in PVC matrix, according to polarizing microscopic observation. The average diameter of the microfibrils becomes smaller in the composite with lower content of PPTA. In the surface region of PPTA microfibrils the intermolecular hydrogen bonds between C? Cl of PVC and N? H of PPTA are formed. Young's modulus and the yield stress at room temperature were higher in the composites than those in PVC. The modulus of the composites was higher, especially at the high temperatures above their glass transition temperatures, than that in PVC. The temperature dependence of modulus can be calculated by using the mechanical model equivalent to the quasi-3-dimensional microfibrillar model which will be approximately applied to the composite structure. It becomes apparent that the modulus of the PPTA microfibrils evaluated by using the mechanical model is higher in the higher molecular weight PPTA. 相似文献
42.
X.M. Tian S. Adhikari S. Adhikary H. Uchida M. Umeno T. Soga T. Jimbo 《Diamond and Related Materials》2005,14(11-12):1839
Nitrogen incorporated diamond like carbon films have been deposited by microwave surface wave plasma chemical vapor deposition (MW-SWP-CVD), using methane (CH4) as the source of carbon and with different nitrogen flow rates (N2 / CH4 flow ratios between 0 and 3). The influence of the nitrogen incorporation on the optical, structural properties and surface morphology of the carbon films were investigated using different spectroscopic techniques. The nitrogen has been incorporated into DLC:N films which was confirmed by the X-ray photoelectron spectroscopy (XPS) measurement. Moreover, the nitrogen incorporation was accompanied by a variation in the optical gap, which was attributed to the removal or creation of band tail states. 相似文献
43.
A method of measurement of solids holdup in a three-phase reactor by analyzing the shape and the phase lag or lead of an ultrasonic wave has been proposed. The solids holdup in a solids-dilute three-phase fluidized bed could be measured without being affected by the presence of gas bubbles. The experimental values of solids axial dispersivity measured by the ultrasonic technique are in reasonable agreement with an empirical correlation of previous data obtained by other methods. The possibility of the application of the ultrasonic technique to the measurement of solids holdup in a three-phase fluidized bed has been suggested. 相似文献
44.
Sudip Adhikari Sunil Adhikary Ashraf M.M. Omer Mohamad Rusop Hideo Uchida Tetsuo Soga Masayoshi Umeno 《Diamond and Related Materials》2005,14(11-12):1824
Nitrogenated diamond-like (DLC:N) carbon thin films have been deposited by microwave surface wave plasma chemical vapor deposition on silicon and quartz substrates, using argon gas, camphor dissolved in ethyl alcohol composition and nitrogen as plasma source. The deposited DLC:N films were characterized for their chemical, optical, structural and electrical properties through X-ray photoelectron spectroscopy, UV/VIS/NIR spectroscopy, Raman spectroscopy, atomic force microscope and current–voltage characteristics. Optical band gap decreased (2.7 to 2.4 eV) with increasing Ar gas flow rate. The photovoltaic measurements of DLC:N / p-Si structure show that the open-circuit voltage (Voc) of 168.8 mV and a short-circuit current density (Jsc) of 8.4 μA/cm2 under light illumination (AM 1.5 100 mW/cm2). The energy conversion efficiency and fill factor were found to be 3.4 × 10− 4% and 0.238 respectively. 相似文献
45.
Recently, compressive sensing-based encryption methods which combine sampling, compression and encryption together have been proposed. However, since the quantized measurement data obtained from linear dimension reduction projection directly serve as the encrypted image, the existing compressive sensing-based encryption methods fail to resist against the chosen-plaintext attack. To enhance the security, a block cipher structure consisting of scrambling, mixing, S-box and chaotic lattice XOR is designed to further encrypt the quantized measurement data. In particular, the proposed method works efficiently in the parallel computing environment. Moreover, a communication unit exchanges data among the multiple processors without collision. This collision-free property is equivalent to optimal diffusion. The experimental results demonstrate that the proposed encryption method not only achieves the remarkable confusion, diffusion and sensitivity but also outperforms the existing parallel image encryption methods with respect to the compressibility and the encryption speed. 相似文献
46.
Thomas Uchida Alfonso Callejo Javier García de Jalón John McPhee 《Multibody System Dynamics》2014,31(3):371-392
Efficient dynamic simulation code is essential in many situations (including hardware-in-the-loop and model-predictive control applications), and highly beneficial in others (such as design optimization, sensitivity analysis, parameter identification, and controller tuning tasks). When the number of modeling coordinates n exceeds the degrees-of-freedom of the system f, as is often the case when closed kinematic chains are present, the governing dynamic equations consist of n second-order ordinary differential equations (ODEs) coupled with m=n?f algebraic constraint equations. This set of n+m index-3 differential-algebraic equations can be difficult to solve in an efficient yet accurate manner. Embedding (or generalized coordinate partitioning) can be used to obtain f ODEs (one for each independent acceleration), which are generally more amenable to numerical integration; however, the dependent positions are typically computed from the independent positions at each time step. Newton–Raphson iteration is often used for solving the position-level kinematics, but only provides solutions to within a specified tolerance, and can require several iterations to converge. In this work, Gröbner bases are used to obtain recursively solvable symbolic solutions for the dependent positions, which can then be evaluated to within machine precision using a fixed number of arithmetic operations. Natural coordinates are particularly attractive in this context, since the resulting constraint equations are maximally quadratic polynomials and are, therefore, easily triangularized. The proposed approach is suitable for use in an automated formulation procedure and, as demonstrated by three examples, is capable of generating highly efficient simulation code with minimal additional effort required at the formulation stage. 相似文献
47.
Local structure and concentration in Al-Mn alloy electrodeposits 总被引:1,自引:0,他引:1
The structures of f.c.c. crystalline and amorphous phases coexisting in Al-Mn alloy electrodeposits containing 11–30 wt% were examined by using the grazing-incidence X-ray diffraction (GIXD) method, high-resolution transmission electron microscopy combined with energy dispersive X-ray spectrometry (HRTEM/EDS), and the manganese K-edge extended X-ray absorption fine-structure (EXAFS) technique. The amorphous and f.c.c. phases were homogeneously distributed in the through-thickness direction of the electrodeposits, although the amorphous phase increased and the f.c.c. phase decreased with increasing manganese total concentration. The decrease of Mn-content in the f.c.c. crystalline phases with increasing manganese total concentration was revealed by the lattice constant measurement of the f.c.c. crystalline phase. This result was also supported by the microarea elemental analysis by HRTEM/EDS. The EXAFS result has indicated that the manganese local structures in the amorphous phases are almost identical in different manganese total concentration electrodeposits. This suggests that the Mn-content in the amorphous phases hardly changes with increasing manganese total concentration. These results have revealed that a peculiar elemental partition occurs in the amorphous and crystalline phases of Al-Mn alloy electrodeposits. 相似文献
48.
Masashi Wada Satoshi Kitaoka Naoki Kawashima Tatsuya Yamada Yoshiyuki Yasutomi Masatoshi Kawai Hideki Inagaki 《Journal of the American Ceramic Society》2006,89(7):2134-2139
Carbon substrates were coated completely with a molten silicate glass, where the wettability of carbon to glass was improved by infiltration and pyrolysis of perhydropolysilazane. Microstructures of the carbon–glass interface were dependent on P n 2 during coating. Coating at lower P n 2 induced the formation of cristobalite at the carbon–glass interface. When the coating was performed at higher P n 2 , the glass and carbon were strongly adhered, without the formation of cristobalite. Coating at higher P n 2 improved the thermal shock resistance of the glass layer, because crack initiation was not induced by the phase transformation of cristobalite during the cooling process. In the case of coating at higher P n 2 , an oxynitride glass layer was formed at the glass subsurface by dissolution of N2 . A porous glass subsurface layer with uniform spherical micro-pores could be produced by soaking near the glass transition temperature in a steam environment. The porous layer with fine and homogeneous microstructure acts as a thermal shock absorbing layer, so that glass-coated carbon with a porous glass layer has excellent thermal shock resistance in addition to steam oxidation resistance. 相似文献
49.
Yoshitsugu Kosugi Tsutomu Kunieda Naoki Azuma 《Journal of the American Oil Chemists' Society》1994,71(4):445-448
Rice bran oil containing 30–50% free fatty acid was continually converted to an oil containing more than 75% of triacylglycerol
(TG) by means of immobilized lipase. The reaction was carried out at 60°C for 24 h with dehydration and reactant mixing by
dry nitrogen flow under a positive nitrogen atmosphere. Enzymatic TG synthesis with evaporation by heating was not suitable
because of the increasing peroxide value of the oil.
Part of this article was presented at the annual meeting of the Japan Oil Chemists' Society at Sendai, Japan, October, 16,
1990. 相似文献
50.
Yoshikazu Suzuki Naoki Kondo Tatsuki Ohji Peter E. D. Morgan 《International Journal of Applied Ceramic Technology》2004,1(1):76-85
Uniformly porous composites with 3-D network structure (UPC-3D) have been recently developed via a pyrolytic reactive sintering process, which takes advantage of the evolved CO2 gas from a decomposing carbonate source (e.g., dolomite, CaMg(CO3 )2 ) and does not require any additional pore-forming agent nor long-time burning-out process. Through liquid formation via LiF doping, strong necks are formed between constituent particles before completion of the pyrolysis of carbonate, resulting in the formation of a strong 3-D network structure. The pore size distribution is very narrow (with typical pore size: ∼1 μm), and the porosity was controllable (∼30–60%) by changing the sintering temperature. This article presents the development details of UPC-3D, and reports the recent findings in CaZrO3 /MgAl2 O4 system, which will be one of the more promising systems for practical applications. 相似文献